FUW TRENDS IN SCIENCE & TECHNOLOGY JOURNAL

(A Peer Review Journal)
e–ISSN: 2408–5162; p–ISSN: 2048–5170

FUW TRENDS IN SCIENCE & TECHNOLOGY JOURNAL

EFFECT OF SODIUM CHLORIDE ON FURFURAL YIELD FROM MICROALGA
Pages: 461-465
A. O. Ameh, J. E. Oguche, Y. Tanimu and S. A. Egu


keywords: Batch reactor, biomass, composition, hemicellulose, NaCl

Abstract

This paper reports a study on the production of furfural from microalga biomass, specifically investigate the effect of sodium chloride (NaCl) on furfural yield from microalga by varying the amount of NaCl (0 to 60 g) at constant reaction temperature, time and acid concentration. Furfural production was carried out by hydrolysis of Pentosans to Pentoses; Pentosans in hemicelluloses is hydrolyzed with dilute mineral acids with NaCl as a promoter with heating to pentoses. Subsequent pentoses are dehydrated to furfural in a single stage process. The proximate analysis of the microalgae biomass shows high percentage content of hemicellulose (54.13%). Results obtained indicated that furfural yield increase with increase in NaCl up to an optimum after which yield dropped. The highest furfural yield of 60.3% was recorded at 30 g of NaCl. Fourier Transform Infrared Spectroscopy (FTIR) result confirm the presence of carbonyl and aldehyde functional groups at wave length of 1674.27 cm-1 and 2924.18 cm-1, respectively while Gas Chromatogram Mass Spectrum(GC-MS) analysis of the sample confirms the presences of furfural (50.86%).

References

Alabi AO, Tampier M & Bibeau E 2009. Microalgae technologies and processes for biofuels/bioenergy production in British Columbia—Current technology, suitability and barriers. A report submitted to The British Columbia Innovation Council, by Seed Science; available at https://www.ctc-n.org/technologies/biofuels-algae. Ambalkar VU & Talib MI 2012. Synthesis of furfural from lignocellulosic biomass as agricultural residues: A review. Int. J. Engr. & Sci. (IJES), 1(1): 30-36. Ameh AO, Ojo AA & Gaiya J 2016. Preliminary investigation into the synthesis of furfural from sugarcane bagasse. FUW Trends in Science & Technologies Journal, 1(2): 582 - 586. Amir S, Ayyaz M, Shahid S, Ziad A, Usman S, and Umar F, (2015) Effect of Acid Concentration on the Extraction of Furfural from Corn Cob. Int. J. Chem. Engr. & Applic., 6(5): 382 – 384. Chen H, Qin L & Yu B 2015. Furfural production from steam explosion liquor of rice straw by solid acid catalysts (HZSM-5). Biomass and Bioenergy, 73: 77-83. Hannon M, Gimpel J, Tran M, Rasala B & Mayfield S 2010. Biofuels from algae: challenges and potential of Biofuels, 1: 763–84. Indira P & Biswajit R 2012. Commercial and industrial applications of micro algae – A review. Journal of Algal Biomass Utln., 3(4): 89–100. Jeon W, Ban C, Eun J, Chul H & Heui D 2016. Chemical production of furfural from macroalgae-derived alginic acid over. Journal of Molecular Catalysis A: Chemical, 423: 264–269. Jones CS & Mayfield SP 2012. Algae biofuels: Versatility for the future of bioenergy. Current Opinion Biotechnol, 23: 346–51. López Baldovín F., García Domínguez MT, Feria Infante MJ, García Domínguez JC, Diego CM, Zamudio MAM & Díaz Blanco MJ 2014. Optimization of furfural production by acid hydrolysis of Eucalyptus globulus in two stages. Chemical Engineering Journal, 240: 195-201. Machado G, Leon S, Santos F, Lourega R, Dullius J, Mollmann ME & Eichler P 2016. Literature review on furfural production from lignocellulosic biomass. Journal of Natural Resources, 7: 115-129. Oguche JE, Ameh AO, Tanimu Y & Egu SA 2017. Determination and optimization of effect of process parameters on furfural yield from microalgae. FUW Trends in Sci. & Techn J., 2(2): 782 – 787. Sweygers N, Raf D & Lise A 2016. Production of levulinic acid and furfural by microwave-assisted hydrolysis from model compounds: Effect of temperature, acid concentration and reaction time. Waste and Biomass Valorization, 9(3): 343-355. Tong X, Ma Y & Li Y 2010. Biomass into chemicals: Conversion of sugars to furan derivatives by catalytic Processes. J. Appl. Catalysis a Review: General, 385: 1–13. Kightlinger W, Chen K, Pourmir A, Crunkleton DW, Price GL & Johannes TW 2014. Production and characterization of algae extract from Chlamydomonas reinhardtii. Electronic J. Biotechn., 17(1): 14-18.

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